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- Beginning at the “relaxed” excited state, the high energy photon decays quickly toward the ground state and emits this excess energy as a photon of light. This transition of energy is what we know as fluorescence.
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Jan 30, 2023 · Fluorescence, a type of luminescence, occurs in gas, liquid or solid chemical systems. Fluorescence is brought about by absorption of photons in the singlet ground state promoted to a singlet excited state. The spin of the electron is still paired with the ground state electron, unlike phosphorescence.
- Photoluminescence, Phosphorescence, and Fluorescence Spectroscopy
Fluorescence: When the chemical substrate undergoes internal...
- Photoluminescence, Phosphorescence, and Fluorescence Spectroscopy
Fluorescence is the phenomenon of absorption of electromagnetic radiation, typically from ultraviolet or visible light, by a molecule and the subsequent emission of a photon of a lower energy (smaller frequency, longer wavelength). This causes the light that is emitted to be a different color than the light that is absorbed.
Apr 5, 2023 · Fluorescence occurs when a material absorbs a photon and transitions from its ground state to an excited state. After a brief period, called the fluorescence lifetime, the material returns to its ground state, emitting a photon with lower energy in the process.
- Emission Spectrum and Intensity
- Fluorescence Decay
- Competing non-radiative Processes
- Fluorescence in Lasers and Amplifiers
- Application in Lighting
- Application in Solar Concentrators For Photovoltaics
- Using Fluorescence in Other Ways
- Interactions Via Fluorescence
- Parametric Fluorescence
- Disturbing Fluorescence
The optical spectrum of fluorescence light (see e.g. Figure 1) generally differs from that of the light which initially caused the excitation of the medium. A significant Stokes shift (difference in photon energies of absorbed and emitted light) can occur because a part of the excitation energy is converted to heat in the medium. For example, the e...
After excitation with a short pulse, the fluorescence decay is often of exponential nature with a decay constant which is called the fluorescence lifetime or upper-state lifetime ( because the fluorescence lifetime is identical to the lifetime of the population in the upper level of an electronic transition). For so-called allowed transitions, the ...
In many cases, there are non-radiative processes which compete with fluorescence and reduce or even fully suppress it (→ quenching). In particular, multi-phonon transitions are very strong for level pairs with an energy distance which is at most a few times the maximum phonon energy of the host material. In other cases, energy transferprocesses can...
In the context of lasers, fluorescence in the laser crystal (or other gain medium) by spontaneous emission is lost for the laser operation because only a tiny fraction of it goes into the laser resonator mode. The fluorescence lifetime for fluorescence from the upper laser level is usually called the upper-state lifetime. Fluorescence is the most f...
Fluorescence is widely used in fluorescent tubes for illumination purposes. The most common fluorescent lamps contain mercury vapor inside a glass tube, where an electric discharge excites the mercury atoms to emit mostly ultraviolet light. A fluorescent material (called the phosphor) on the inner surface of the tube absorbs the ultraviolet light a...
Fluorescence in transparent polymer sheets, which are doped with some luminescent species, can be used for luminescent (or fluorescent) solar concentrators . Sunlight hitting the polymer sheets from any direction can be absorbed and efficiently transformed into fluorescent light, which is partly trapped in the sheets and thus sent to the edges, whe...
Fluorescence light can be useful, e.g. for direct use for optical measurements, such as for measuring the transmission spectra of optical devices. It is also the basis of fluorescence spectroscopy, fluorescence microscopy and of optical refrigeration. By combining multiple types of emitting rare earth ions in an optical fiber, very broadband radiat...
Fluorescence of the single atoms, ions or molecules of a sample usually occurs in an uncoordinated manner, i.e., uniformly in all spatial directions and without temporal correlations between the emitted photons. However, certain conditions lead to amplified spontaneous emission (superluminescence) or superfluorescence, where this is no longer the c...
A special kind of fluorescence, which is not related to the excitation of atoms or ions in a substance, is parametric fluorescence in nonlinear crystal materials. This effect does not involve the excitation of electrons in the media, but rather a nonlinear interaction. Such fluorescence occurs only as long as some pump light propagates in the mediu...
Fluorescence effects can be quite disturbing under certain circumstances. For example, certain spectroscopicmeasurements can be disturbed by unwanted laser-induced fluorescence in glass windows or tubes. Such fluorescence often originates from certain impurities.
Jun 2, 2023 · This article gives an introduction to fluorescence and photoluminescence, which includes phosphorescence, explains the basic theory behind them, and how fluorescence is used for microscopy.
Aug 28, 2022 · Fluorescence: When the chemical substrate undergoes internal energy transitions before relaxing to its ground state by emitting photons, some of the absorbed energy is dissipated so that the emitted light photons are of lower energy than those absorbed.
Oct 9, 2024 · Fluorescence, emission of electromagnetic radiation, usually visible light, caused by excitation of atoms in a material, which then reemit almost immediately (within about 10−8 seconds).
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