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- The rate of evaporation in an open system is related to the vapor pressure found in a closed system. If a liquid is heated, when the vapor pressure reaches the ambient pressure the liquid will boil. The ability for a molecule of a liquid to evaporate is based largely on the amount of kinetic energy an individual particle may possess.
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Aug 14, 2020 · As the temperature of a liquid increases, the vapor pressure of the liquid increases until it equals the external pressure, or the atmospheric pressure in the case of an open container. Bubbles of vapor begin to form throughout the liquid, and the liquid begins to boil.
- Vapor Pressure
Will the vapor pressure of the liquid increase or decrease?...
- 13.8: Vapor Pressure
Vapor pressure is a measure of the pressure exerted by a gas...
- Vapor Pressure
- Factors That Affect Vapor Pressure
- Vapor Pressure of Water
- How to Calculate Vapor Pressure
- References
The most important factors affecting vapor pressure are temperature and type of molecules: 1. Temperature: Temperature has the greatest effect on vapor pressure. As temperature increases, vapor pressure increases. As temperature decreases, vapor pressure decreases. This makes sense, as imparting thermal energy gives molecules more kinetic energy. T...
The vapor pressure of water depends on its temperature. The vapor pressure of water at room temperature (25 °C) is 23.8 mm Hg, 0.0313 atm, or 23.8 torr, or 3.17 kPa. At its freezing point (0 °C), the vapor pressure of water is 4.6 torr. At its boiling point (100 °C), the vapor pressure of water is 658.0 torr (atmospheric pressure).
There are several vapor pressure formulas, but two common ones are Raoult’s law and the Clausius-Clapeyron equation.
Perry, R.H.; Green, D.W., eds. (1997). Perry’s Chemical Engineers’ Handbook(7th ed.). McGraw-Hill. ISBN 978-0-07-049841-9.Petrucci, Ralph H.; Harwood, William S.; Herring, F. Geoffrey (2002). General Chemistry(8th ed.). Prentice Hall. ISBN 978-0-13-014329-7.Sinnot, R.K. (2005). Chemical Engineering Design(4th ed.). Butterworth-Heinemann. ISBN 978-0-7506-6538-4.Wagner, W. (1973). “New vapour pressure measurements for argon and nitrogen and a new method for establishing rational vapour pressure equations”. Cryogenics. 13 (8): 470–482. doi:10.1016/0011-2275...Jan 30, 2023 · Will the vapor pressure of the liquid increase or decrease? It turns out that having a nonvolatile solute in the liquid will decrease the vapor pressure of the liquid because the solutes will interfere with the high-energy liquid molecules' path to the surface to break free into the gaseous phase.
Sep 21, 2022 · Vapor pressure is a measure of the pressure exerted by a gas above a liquid in a sealed container. Strong intermolecular forces produce a lower rate of evaporation and a lower vapor pressure. Weak intermolecular forces produce a higher rate of evaporation and a higher vapor pressure.
A liquid’s vapour pressure is a vapour’s equilibrium pressure above its liquid (or solid); that is, the vapour pressure resulting from a liquid (or solid) evaporation above a liquid (or solid) sample in a closed container.
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- Raoult’s law is a chemical law that relates the solution’s vapour pressure to the mole fraction of a solution added. The law of Raoult is expressed...
- When a liquid’s vapour pressure is the same as the atmospheric pressure, the material is at temperature and pressure at the boiling/freezing point....
- As a result, there are lower boiling points of liquids with high vapour pressure. By heating a liquid and allowing more molecules to enter the atmo...
- The material with the lowest boiling point would, therefore, have the highest vapour pressure at room temperature (the easiest way to reach the gas...
Vapor pressure [a] or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate.
The identity of the liquid will also affect the vapor pressure because the strength of the intermolecular forces between the molecules of a liquid affects the rate of evaporation. If the intermolecular forces are weak, it will require less energy for molecules of that substance to become a vapor.
