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- Water vapor takes up more space than an equal mass of liquid water. As a result, in a closed container, the vapor that forms can exert a significant amount of pressure. This pressure is known as vapor pressure. Even in an open container, the vapor is confined by the air pressing down on it. Some of it collects at the surface and exerts pressure.
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Vapour pressure, also known as vapour equilibrium pressure, can be defined as the pressure exerted (in a system featuring thermodynamic equilibrium) by a vapour with its condensed phases (solid or liquid) in a closed system at a given temperature.
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- A liquid’s vapour pressure is a vapour’s equilibrium pressure above its liquid (or solid); that is, the vapour pressure resulting from a liquid (or...
- Raoult’s law is a chemical law that relates the solution’s vapour pressure to the mole fraction of a solution added. The law of Raoult is expressed...
- When a liquid’s vapour pressure is the same as the atmospheric pressure, the material is at temperature and pressure at the boiling/freezing point....
- As a result, there are lower boiling points of liquids with high vapour pressure. By heating a liquid and allowing more molecules to enter the atmo...
- The material with the lowest boiling point would, therefore, have the highest vapour pressure at room temperature (the easiest way to reach the gas...
- Factors That Affect Vapor Pressure
- Vapor Pressure of Water
- How to Calculate Vapor Pressure
- References
The most important factors affecting vapor pressure are temperature and type of molecules: 1. Temperature: Temperature has the greatest effect on vapor pressure. As temperature increases, vapor pressure increases. As temperature decreases, vapor pressure decreases. This makes sense, as imparting thermal energy gives molecules more kinetic energy. T...
The vapor pressure of water depends on its temperature. The vapor pressure of water at room temperature (25 °C) is 23.8 mm Hg, 0.0313 atm, or 23.8 torr, or 3.17 kPa. At its freezing point (0 °C), the vapor pressure of water is 4.6 torr. At its boiling point (100 °C), the vapor pressure of water is 658.0 torr (atmospheric pressure).
There are several vapor pressure formulas, but two common ones are Raoult’s law and the Clausius-Clapeyron equation.
Perry, R.H.; Green, D.W., eds. (1997). Perry’s Chemical Engineers’ Handbook(7th ed.). McGraw-Hill. ISBN 978-0-07-049841-9.Petrucci, Ralph H.; Harwood, William S.; Herring, F. Geoffrey (2002). General Chemistry(8th ed.). Prentice Hall. ISBN 978-0-13-014329-7.Sinnot, R.K. (2005). Chemical Engineering Design(4th ed.). Butterworth-Heinemann. ISBN 978-0-7506-6538-4.Wagner, W. (1973). “New vapour pressure measurements for argon and nitrogen and a new method for establishing rational vapour pressure equations”. Cryogenics. 13 (8): 470–482. doi:10.1016/0011-2275...Mar 13, 2023 · Vapor pressure is the pressure inside a closed container when a liquid is in equilibrium with its own gas phase so the rate of evaporation is equal to the rate of condensation. When a non-volatile solute is dissolved in a volatile solvent, the vapor pressure of the solvent is reduced.
Apr 12, 2023 · The vapor pressure of liquid SO 2 is 33.4 torr at −63.4°C and 100.0 torr at −47.7 K. What is the ΔH vap of SO 2? What is its vapor pressure at −24.5 K? At what temperature is the vapor pressure equal to 220 torr?
Nov 21, 2023 · The vapor pressure is the pressure exerted by vapor at equilibrium with its solid or liquid in a closed chamber. It can be calculated either by using Clausius-Clapeyron Equation or...
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Vapor pressure can be measured in various ways. Use this quiz and worksheet to check your understanding of the characteristics of vapor pressure and the calculation of vapor pressure.
Feb 5, 2019 · This example problem demonstrates how to use Raoult's Law to calculate the vapor pressure of two volatile solutions mixed together. Raoult's Law Example. What is the expected vapor pressure when 58.9 g of hexane (C 6 H 14) is mixed with 44.0 g of benzene (C 6 H 6) at 60.0 °C? Given: Vapor pressure of pure hexane at 60 °C is 573 torr.
