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  1. Jan 16, 2023 · The easiest terms to define are the ones used to describe the system of interest and the surroundings, both of which are subsets of the universe. Universe – everything. System – subset of the universe that is being studied and/or measured. Surroundings – every part of the universe that is not the system itself.

  2. In the world of chemistry, the system is the chemical reaction. For example: 2H 2 + O 2---> 2H 2 O The system consists of those molecules which are reacting. The surroundings are everything else; the rest of the universe. For example, say the above reaction is happening in gas phase; then the walls of the container are part of the surroundings.

  3. Apr 13, 2022 · The boundary is the closed three-dimensional surface that encloses the system and separates it from the surroundings. The boundary may (and usually does) coincide with real physical surfaces: the interface between two phases, the inner or outer surface of the wall of a flask or other vessel, and so on. Alternatively, part or all of the boundary ...

  4. Nov 26, 2018 · Equilibrium between System and Surroundings. – If the state of the system shows no tendency to change, we say that the system is at equilibrium with the surroundings. – The equilibrium condition is a fundamental consideration of thermodynamics. – Although not all systems are at equilibrium, we almost always use equilibrium as a reference ...

  5. The surroundings are the vessel, the piston, and everything else. The reaction is: H 2 (g) + I 2 (g) → 2 H 2 I (g) Energy is released as the reaction proceeds to form gaseous hydrogen iodide. As the reaction proceeds, energy is transferred from the system to the surroundings. The mass remains the same, and it is only the form of the hydrogen ...

  6. Jun 5, 2024 · Patrick E. Fleming (Department of Chemistry and Biochemistry; California State University, East Bay) This page titled 5.5: Comparing the System and the Surroundings is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by Patrick Fleming. It is oftentimes important to calculate both the entropy change of the system ...

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  8. The system is the collective substances in the reaction such as the reactants and products. The surroundings are everything around the reaction such as the reaction flask and the room. During a reaction, energy is transferred between the system and surroundings. This energy is a sum of all potential and kinetic energies.

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